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[Janosik-user] ridiculously


From: Tom Townsend
Subject: [Janosik-user] ridiculously
Date: Thu, 5 Oct 2006 13:58:29 +0200
User-agent: Thunderbird 1.5.0.7 (Windows/20060909)


O hydrogen bonds to give a three-dimensional molecular network.
The two imino groups are hydrogen bonded with the dimethyl sulfoxide solvent molecule. The crystal structure contains three very weak intermolecular hydrogen bonds, viz. O hydrogen bonds, forming centrosymmetric carboxylic acid dimers. O hydrogen-bond acceptor to the amide and amine groups of two adjacent molecules, resulting in a layered structure.
O hydrogen-bond acceptor to the amide and amine groups of two adjacent molecules, resulting in a layered structure. N hydrogen bonding between neighboring molecules helps to stabilize the crystal structure.
The molecule contains a centre of inversion at the mid-point of the central double bond and the thiazine rings have an envelope conformation. The two imino groups are hydrogen bonded with the dimethyl sulfoxide solvent molecule.
The crystal structure contains three very weak intermolecular hydrogen bonds, viz. N hydrogen bonds into infinite chains. Each of the cis-fused tetrahydrofuran rings adopts an envelope conformation with the O atom in the flap position.
The water molecule lies on a twofold axis. O hydrogen bonds to give a three-dimensional molecular network. The structure comprises two molecules in the asymmetric unit, which differ in terms of the orientation of their pendant n-propyl groups. O hydrogen bonds, which may be effective in the stabilization of the crystal structure.
O hydrogen bonds complete a two-dimensional hydrogen-bond network. O hydrogen bonds complete a two-dimensional hydrogen-bond network. O hydrogen bonds link the molecules into two-dimensional layers. S intermolecular interactions.
The nitro group is almost coplanar with the benzene ring to which it is attached.
O hydrogen bonds, forming centrosymmetric carboxylic acid dimers. In the molecule, two thiazoline rings are located on one side of the central benzene plane, while the third thiazoline ring is located on the other side of the central benzene plane.
The molecule occupies a special position on a twofold axis and the saturated ring has a half-chair conformation. O hydrogen bonds link molecules into one-dimensional chains along the b-axis direction.
An intramolecular hydrogen bond links the NH group to an O atom of the nearest nitro group. The water molecule lies on a twofold axis. The six-membered rings have chair conformations, while the conformation of the five-membered ring is an envelope.
S intermolecular hydrogen bonds, forming a two-dimensional network.
O hydrogen bonds help to consolidate the crystal structure. Cl hydrogen bonds, forming a chain along the c axis.
N hydrogen bonding between neighboring molecules helps to stabilize the crystal structure.
The crystal structure contains three very weak intermolecular hydrogen bonds, viz.
The water molecule lies on a twofold axis.
In the molecule, two thiazoline rings are located on one side of the central benzene plane, while the third thiazoline ring is located on the other side of the central benzene plane.
O hydrogen bonds help to consolidate the crystal structure. O hydrogen bonds link the molecules into chains running along the a axis.


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