The bond lengths within the system indicate some
degree of delocalization. S hydrogen bond stabilizes the molecular
structure.
O intermolecular hydrogen bonds.
In the molecule, two thiazoline rings are located
on one side of the central benzene plane, while the third thiazoline ring is located
on the other side of the central benzene plane.
An intramolecular hydrogen bond links the NH group
to an O atom of the nearest nitro group.
N hydrogen bonds link the molecules into
centrosymmetric dimers. Cl hydrogen bonds link cations and anions to form
one-dimensional ladders propagating in the a-axis direction. N hydrogen-bonding
interactions.
S intermolecular hydrogen bonds, forming a
two-dimensional network.
O hydrogen bonds link the molecules into chains
running along the a axis. O hydrogen bonds link the molecules into zigzag chains
along the b axis. O intermolecular hydrogen bonds.
An intramolecular hydrogen bond links the NH group
to an O atom of the nearest nitro group. O hydrogen bonds link the molecules into
columns along the a axis. O hydrogen bonds, resulting in inversion-symmetry
generated dimers. O hydrogen bonds link the molecules into dimers, which may be
effective in the stabilization of the crystal structure. O hydrogen bonds that form
centrosymmetric dimers.
The latter links molecules into infinite chains. O
hydrogen bonds link the molecules into chains extended along the b axis. S
intermolecular hydrogen bonds, forming a two-dimensional network.
The crystal packing is further stabilized by van
der Waals forces. N interactions connect these chains into a two-dimensional layer.