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crabby sultan


From: Jennie Snow
Subject: crabby sultan
Date: Thu, 19 Oct 2006 13:14:11 +0300
User-agent: Thunderbird 1.0.8 (Windows/20060417)


The pyrazole ring is in an envelope conformation. O interactions help to form chains of molecules in the crystal structure.
O intramolecular hydrogen bonds lead to the formation of a sequence of five-, six- and five-membered rings, respectively, which are edge-fused.
O interactions form a hydrogen-bonded network. There is a centre of symmetry at the centre of each cation ring. O interactions help to form chains of molecules in the crystal structure.
The pyridyltetrazolate anions serve to bridge the different copper ions into an almost flat ribbon. There is a centre of symmetry at the centre of each cation ring.
The triazole ring is almost coplanar with the pyrimidine ring. O hydrogen bonds to form centrosymmetric hydrogen-bonded dimers.
O hydrogen bonds and by short Cl.
S interactions promote two-dimensional packing parallel to the ac plane, and form a three-dimensional network. The title compound is isostructural with the chloro compound.
O hydrogen bonds between the carboxyl groups. O intramolecular hydrogen bonds lead to the formation of a sequence of five-, six- and five-membered rings, respectively, which are edge-fused.
The structure consists of chains running along the a axis.
The are two molecules in the asymmetric unit. O hydrogen bonds between the carboxyl groups.
Each ligand provides one O atom and one N atom. The structure consists of chains running along the a axis.
O hydrogen bonds link the molecules, forming a network, which may be effective in the stabilization of the crystal structure.
O interactions are found in the crystal structure.
Each molecule is nearly planar and they are roughly parallel to each other.
The diacid anions and uncoordinated water molecules fill the space between the layers. The structure consists of chains running along the a axis.
O hydrogen bonds, linking the independent molecules into dimers, may be effective in the stabilization of the crystal structure.
S interactions promote two-dimensional packing parallel to the ac plane, and form a three-dimensional network.
O interactions are found in the crystal structure.


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